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The invention of Fourier Transform IR (FT-IR) spectroscopy has
proven to be one of the most important advances in modern instrumentation
development. Optical spectroscopy utilizing the interference of
light waves has made fast, sensitive detection of molecular vibration/rotation
possible due to the large throughput and multiplex advantages
provided by FT instrumentation. Interestingly enough, the same
technological innovations, which have made FT-IR the instrument
of choice for over thirty years, have also made FT-IR instruments
extremely sensitive to their operating environment. As a result,
the need for thermal stability, mechanical vibration isolation
and stringent optical alignment have put severe limitations on
where and how an FT-IR instrument can be used, confining it, for
the most part, to the laboratory environment. Current FT-IR instruments
use a scanning mirror, need to be purged with nitrogen in order
to avoid interference from atmospheric water vapor and carbon
dioxide and use single element detectors.
Planar Array IR (PA-IR), on the other hand, uses a focal plane
array (FPA) detector onto which a beam of light dispersed by a
prism or grating is focused. The broad range of frequencies displayed
on the pixel array simultaneously make this a multiplex technique
without using the complex scanning mechanism or computational
requirements (for Fourier transformation of the data) used in
FT-IR instruments. Thus the no-moving parts configuration of the
PA-IR instrument provide the ruggedness required to make the instrument
the size of a "shoe-box" and hence portable. In addition
the increased sensitivity (100-1000X over single element FTIR
detectors) of the FPA allows an IR spectrum to be accumulated
in as little as 10 microseconds. The only current limitation comes
from the frequency range available (3400-2000 cm-1) due to the
initial availability of only indium-antimonide FPAs during the
development of the prototype. With the impending availability
of Hg-Cd-Te (MCT) FPAs, the available bandwidth of PA-IR instruments
will be increased to include the IR " fingerprint "
region (1800-750 cm-1) without an appreciable loss of sensitivity
and speed. Hence many new applications including on-line processing
and studies in molecular/polymer dynamics will now be possible
using state-of-the-art PA-IR instrumentation.
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